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The strain measurements obtained during the relaxation frame using a DP of 5 mm proved to be a well-performing TDI-Q setting for the cervical TS measurement.
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From proton rotating frame relaxation data we derive a high rate of translational diffusion in the chain direction.
This "cheese-wiring" effect (Fig. 4) caused relaxation of the frame when returning to knee extension and therefore a loss of protection of ligament suture.
An extensive study of both 1H and 13C Tl (spin-lattice) and Tlρ (spin-lattice in the rotating frame) relaxation times as well as TCH (proton carbon cross-polarisation times) was undertaken in order to investigate the morphology and dynamics of an ethylene/propylene/ethylidene-norbornene terpolymer and two ethylene/propylene random copolymers obtained using different catalytic systems.
Several relaxation time parameters (rotating frame and laboratory frame proton and carbon relaxation times) were determined.
Solid state 13C NMR measurements were carried out to determine the several relaxation time parameters; rotating frame and laboratory frame proton and carbon relaxation times.
Laboratory-frame relaxation data were analyzed using the Lipari Szabo model-free formalism.
The definition of τ shows that laboratory-frame relaxation is sensitive to processes with τe ≤ τm, typically picosecond nanosecond for proteins studied by solution NMR spectroscopy.
Traditional H rotating-frame relaxation times that allow for abundant-spin diffusion, ⟨ T1ρ(H ⟩, were measured from the decay of carbon signal intensities with C H contact time in a CPMAS experiment.
Site-specific rotating-frame relaxation times, T1ρ(H), for each H nucleus directly bonded to an observed C nucleus, were measured with a Lee Goldburg (LG) spin lock and LG cross-polarization period to suppress H spin diffusion; the experiments used a short 0.5 ms LGCP time and included 62 106 kHz LG pulses in separate trials.
The TS values were then calculated during the relaxation phase (from the frame of maximal compression to the frame of the subsequent maximal relaxation).
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