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Control experiments further confirmed that PBA did not prevent the reductive separation of CTA1 from CTA2 (Fig. S1).
Previous work has shown that complete reductive separation of CTA1 from CTA2 occurs within 1 minute of β-ME addition [11].
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The development of scalable, one pot, reductive separations provides a useful new approach to SWCNT purification.
However, the decrease of the peak separation between reductive and oxidative waves and the significant improvement of switching times (one of the most important properties of electrochromic materials) were demonstrated.
The main technology is electrorefining for U and Pu separation and reductive-extraction for TRU separation, which can be applied on oxide fuels through reduction process as well as metal fuels.
Furthermore, the bite angle of the ligand could affect the ratio of branched (383) to linear (384) products, with small-bite-angle ligands increasing the C1 C1′ separation and disfavoring 1,1′ reductive elimination.
We have recently shown that glycans isolated from natural sources and labeled with fluorescent tags such as 2-AA and 2-AB using reductive amination are not only suitable for many separation techniques with fluorescence and mass-spectrometric detection (see " Separation methods"), but can also directly be used for covalent immobilization on a natural glycan microarray [ 202] (Fig. 9).
For a variation of the separation argument, sometimes used against reductive realism, see Klima's discussion of Psueudo-Campsall vs. Ockham in Spade 1999, esp.
The lack of kinetic separation of the oxidative and reductive pathways in mammalian cells contrasts sharply with the equivalent systems for native disulfide formation within the bacterial periplasm.
Second, reductive realists also relied on various forms of what is sometimes called 'the separation argument'.
PGC is the separation method of choice for direct liquid chromatography (LC)–MS analysis of O-glycans which have been released by reductive β-elimination, as these glycans are often rather small and do not contain a reducing end for labeling [ 172, 173].
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