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The SPL development approach promotes benefits such as cost reduction, product quality, productivity and time to market (Clements and Northrop 2001).
Overall faradaic efficiency corresponding to CO2 reduction product is 39.6%, whereas hydrogen production is suppressed to 4.5% till the ERC operation of 50 minutes.
These adlayers can be reductively stripped from the electrode surface yielding dissolved ammonium as the main reduction product in acidic solution.
The initial reduction product is adsorbed ferrous ion, Feads2+.
The reduction product or products passivate HMDE surface.
The reduction product CaS is oxidized to SO2 during the oxidizing step.
The main CO2 reduction product is methanol, and the yield of which reaches 35 mmol L−1 at 350 min.
Isotope experiments using 13CO2 as a substrate clearly revealed that CO was generated as a main reduction product of CO2.
Carbon monoxide is detected as a volatile reduction product at potentials more negative than −1.4 V vs.AgAgCl.
Dithionite was found to be the reduction product in acetonitrile, whereas in methanol only hydrogen was formed.
However, DEC exhibited a different reduction product when used in EC/DEC and EC/PC/DEC solvent systems.
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