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The decrease in Jsc was because of the reduction of dye regeneration and the catalytic activity of the photocathode in electrolyte regeneration.
We will report that the addition of BFO improved performances due to the reduction of dye aggregation due to BFO's pzc of pH 6.5 which is close to the pH 5 of the dye solution, as well as BFO's role as an electron blocking layer which prevents the back tunneling of electrons from ZnO to CuSCN.
In contrast, the very high QY for the photocatalysed reduction of DCIP is due to the presence of a vast excess of glycerol which traps the photogenerated holes efficiently and so allow time for the slower reduction of dye to take place.
In order to identify the mechanism of reduction of dye with AuNPs, fluorescence lifetime studies were conducted.
Upon addition of NaBH4, the absorption band intensity decreased gradually, indicating the progress of the reduction of dye.
The reduction of dye eosin by NaBH4 was studied as a model reaction to probe the catalytic activity of chitosan-capped AuNPs.
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The highest performance is achieved in 1.0 wt% BaTiO3 addition as a result of increased photocurrent density (Jsc) and fill factor (FF), regardless of reduction of dye-loading.
Open image in new window Figure 2 Comparison of bacteria reduction of dyed sample.
In the absence of sodium borohydride, the reduction of dyes by AuNPs did not take place.
Besides, many researchers have reported the reduction of dyes using various metal nanoparticles [19 27].
Moreover, catalysis of the reduction of dyes by sodium borohydride (NaBH4) can be enhanced by using silver nanoparticles immobilized on silica spheres.
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