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Coke was found predominantly in the top zone of the bed, suggesting pore blockage by excessive cracking (which probably occurred at higher temperatures) and reduced diffusion limitation compared with other zones.
The decline in Ca correlates with the concentration increase of boric acid species due to a reduced diffusion limitation (see time dependence of Rp) and mirrors also the constant level after 16 min.
The increase of Rp towards more negative values could be due to an increase in the concentration of boric acid in the pores with increasing deposition time as a result of a reduced diffusion limitation, since the Co nanowires grow towards the pore openings reducing the effective pore depth.
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The presence of textural mesoporosity in HMS reduced diffusion limitations, and consequently increased the incorporation of sulfonic groups and their accessibility, leading to higher catalytic activity.
For porous materials such as zeolites, the pore distribution of the active catalyst may be important as samples of higher mesoporosity allow faster reactions due to reduced diffusion limitations (Lungstein et al. 1999; Komatsu 2010).
There has been growing interest in the research and development of hierarchical zeolites possessing at least two levels of porosity in order to reduce diffusion limitations in reactions catalyzed by microporous zeolites.
Aquatic species possess morphological and anatomical leaf traits that reduce diffusion limitations to CO2 uptake and thus aid PN under water.
Breathing carbogen is known to reduce diffusion-limited hypoxia.
Additionally, reduced circulatory sRAGE levels are associated with more severe airflow limitation [ 8, 9], reduced diffusion capacity, and emphysema [ 6, 8] in COPD patients.
It should be noted that reduced diffusion occurring in fixed tissues may influence signal attenuation, which at the employed diffusion weighting (b = 800 s/mm) in theory can bias diffusion sensitivity towards the fast diffusion component in the tissue.
When enzyme kinetics dominate, the concentration gradient is low and the overall kinetics are determined by the total amount of active enzyme, reducing either enzyme concentration or enzyme layer thickness will reduce the diffusion limitation.
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