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Several water molecules are involved in these rearrangement processes.
Detailed analyses of these structures revealed that microhomologies are predominantly involved in rearrangement processes.
We show that in our experiments they mainly results from the electron impact on desorbed species from the reactor wall and not from rearrangement processes.
However, the application of microreactors could significantly increase the safety of both traditional and organocatalyzed Beckmann rearrangement processes with making inventories much smaller.
The two remaining complex rearrangements did not display signs of DSBs and contain duplications, indicative of rearrangement processes involving template switching.
It is argued that grain rearrangement processes accompanying grain growth will tend to mask the development of an elongated grain structure predicted by diffusion creep processes.
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This study explores the influence of synthesis route and ortho-position functional group on the thermal rearrangement process and the fractional free volume of thermally rearranged (TR) polymers produced from polyimides derived from 3,3′-dihydroxy-4,4′-diamino-biphenyl 3,3′-dihydroxy-4,4′-diamino-biphenyl 3,3′-dihydroxy-4,4′-diamino-biphenyl 3,3′-dihydroxy-4,4′-diamino-biphenyl 3,3′-dihydroxy-4,4′-diamino-biphenyl
The rearrangement process seems to be more favorable than the decomposition of CHA to carbene formation.
These species are supposed to proceed via SiMe3+ ion rearrangement process.
As shown in Figure 4, the potential energy surface of rearrangement process contains two transition states and diradical intermediate.
Furthermore, the grain packing is compacted due to a rearrangement process caused by the pulsating movement of air channels.
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