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Subsequently, ceramic nanoparticles with varying chemical composition were prepared for changing the material surface reactivity in terms of the increase in, degradability, surface pH and protein adsorption.
The intrinsic chemical reactivity in terms of the Fukui function, applying the principle of hard and soft acids and bases (HSAB) in the framework of the density functional theory (DFT), was investigated.
By keeping the fuel mole fraction in the mixture constant, the order of reactivity, in terms of inverse ignition delay, is measured to be ϕ = 0.5 > ϕ = 1.0 > ϕ = 1.5, demonstrating the dependence of the ignition delay on oxygen concentration.
A non-linear fit to the experimental data is performed and the reactivity, in terms of the inverse of ignition delay, shows nearly second order dependence on the initial oxygen mole fraction and slightly greater than first order dependence on initial fuel mole fraction and compressed pressure.
The effect of soot surface reactivity, in terms of the evolution of sites on the soot particles' surface available for reaction with gas phase species, is investigated via modeling numerous ethylene/air flames, using a detailed combustion and sectional soot particle dynamics model.
As suggested before, there is a clear link between surface area (i.e. particle size) and reactivity in terms of electron transfer and dissolution (Table 2, Additional file 1: Figures S1 and S4).
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The HDS of dibenzothiophene, 4-methyldibenzothiophene, and 4,6-dimethyldibenzothiophene polyaromatic sulfur compounds present in LCO—and their relative reactivities in terms of conversion were examined as a function of time on stream in a fixed-bed flow reactor.
We offer some simple molecular recognition models to account for the importance of these different structural features in the structure-activity relationships that permit one to express PCB reactivities in terms of dioxin, thyroxine, and estradiol equivalents.
RO isolation under low pressure conditions designed to maximize DOM recovery had little effect on DOM reactivity evaluated in terms of nanofiltration membrane fouling, XAD-8 resin adsorption, activated carbon adsorption, competition with trichloroethylene for adsorption sites on activated carbon, and molecular weight distribution measured using size exclusion chromatography.
The enhanced reactivity is rationalized in terms of the synergy of Ru and Pt.
Some elements relative to the structure, the synthesis, and the reactivity of SMAs in terms of making and cleaving bonds, and their physicochemical and biological behaviors are detailed.
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