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Tremendous interest has been shown in the controllable synthesis and application of anatase TiO2 nanomaterials with high percentage of reactive facets.
In this work, a fluoride mediated hydrothermal method is proposed for the synthesis of TiO2 mesocrystals (MC) exposed by highly reactive facets.
The designed fabrication of mesocrystals with exposed reactive facets provides an attractive and effective route for improving the performances of semiconductor photocatalysts.
This construct is a one-dimensional (1D) nanostructure (i.e., nanowire) with interconnected nanoparticles on the surface with a large percentage of reactive facets, so called corn-like nanowire.
Photocatalytic activity of the as-prepared ZnO nanocrystals with various (0 0 2) orientations in degradation of methyl orange was studied, it was found that the exposed {0 0 1} facets are reactive facets.
The charge separation model may provide new insights into the understanding of charge transfer in the semiconductor nanomaterials with reactive facets and the design of advanced photocatalysts and photoelectronic devices.
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The present study indicates that it's important to take into consideration of various factors in designing efficient photocatalysts, but not only to expose the high-reactive facets.
This work demonstrates that a synergetic mechanism between high-reactive {001} facet of anatase TiO2 and hetero-structured characteristics contributes to enhancing their PEC activities and according photoelectrochemical properties, which can be extended to other binary compounds with high-reactive facets.
Finally, the calculation of the chemisorption energy of oxygen on ZnO crystal facets also proves the reactive-facet-enhanced gas sensitivity.
Thus, the calcination temperature should be carefully controlled to maintain the exposed highly reactive {001} facets.
Synthesis of reactive exposing facets and p-n junction are of great importance for semiconductor photocatalysis.
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