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In contrast, kinetics of dissolution and precipitation reactions is found to be necessary for a better reproduction of the experimental observations in the argillite samples compared to thermodynamic equilibrium calculations, in particular with respect to the extent of the alkaline perturbation.
As a result, the distribution of endothermicity and exothermicity throughout the flame and for particular reversible reactions is found to be a function of the flow environment, which overcomes a major drawback of single-step models, namely a fixed heat of combustion independent of environmental conditions, or one that must be determined separately from the model itself.
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More than 10 kinds of side reactions are found.
The selectivity in all the above reactions was found to be >99%.
Yet geochemical reactions are found to be very slow in the reservoir.
The heat conduction through electrodes and the heat production by the electrode reactions are found to play an important role.
Kinetic parameters for all of the reactions are found by fitting reactor simulations to an extensive experimental database.
For Amberlyst™ 46, however, side reactions were found to be almost negligible.
The reactions were found to be controlled by mass transfer limitations caused by coke deposition.
Cysteine and tyrosine residues were found to be reactive to succinimidyl ester, and the bonds formed through these reactions were found to be labile.
The autocatalytic kinetic model of the chlorination reactions was found to be numerically very unstable.
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