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Three parameters were examined, namely AgBr content in catalysts ([wt%]AgBr), incident light intensity (I0) and catalyst loading (Wcat) in reaction suspension.
Effect of the Fe-rich soil colloids and adding Fe(II) and oxalic acid on reductive dechlorination transformation of pentachlorophenol (PCP) were studied on colloids interfaces of reaction suspension.
The reaction suspension was agitated overnight.
Reaction suspension was irradiated by UV light of 365 nm at a power of 18 W.
The reaction suspension was prepared in the same fashion as in the adsorption experiments.
At different irradiation time intervals, analytical samples were taken from the reaction suspension and centrifuged to remove the photocatalyst particles.
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After a four-hour digestion, reaction suspensions were centrifuged and the supernatants were discarded, in order to remove soluble protein.
After the reaction, the suspension of the engineered NPs were collected by centrifugation and further washed twice by distilled water for purification.
After 10 minutes of reaction the suspension of magnetite (Fe3O4) was sedimented by applying a magnetic field gradient and washed three times with water until the pH reached 7. The naked SPION were then redispersed in 400 ml and oxidized with 160 ml of nitric acid (HNO3 at 2 M) and 240 ml of ferric nitrate (Fe(NO3 3 at 0.35 M) under reflux for 90 minutes.
While individual particles may not be able to ignite, the collective effect, which results from the self-heating of particle suspensions to thermal runaway, can enable fast reaction in suspensions.
None of us added a warning label: "Follow this advice at your own risk; possible adverse reactions include suspension and loss of your job".
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com