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The mechanism of the topographical changes on the reacted surface that led to these results was also verified by atomic force microscopy (AFM).
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According to the scanning electron microscopy (SEM) images of the chars, those obtained in the CO2 atmosphere experienced a greater degree of swelling, some particles showing partially reacted surfaces indicative of reaction between the char and CO2.
The model-fit surface area, here termed reacting surface area, was much smaller than the BET-measured surface area determined for powdered basaltic material.
In the parent basalt, reacting surface area and diffusivity are low due to low pore connectivity, and early weathering is therefore transport controlled.
However, as pore connectivity increases as a result of weathering, the reacting surface area and diffusivity also increase and weathering becomes controlled by mineral reaction kinetics.
This can be explained by the evolution of the reacting surface area which is described by a modified random pore model.
It is shown that the fractional change of reacting surface area of the solid reactant can be obtained using the CFBR under the limiting condition of negligible effect of mass transfer.
Two different types of kinetics are observed, depending on the oxygen coverage and it is argued that the changeover is largely due to a change in embedding conditions, while the reacting surface molecule is unchanged.
The end walls in the chamber are described as uniform and locally reacting surfaces.
Catalytic reacting surfaces in recombiners are a reliable way to remove hydrogen as well as other burnable gases like CO in a passive way from the containment atmosphere of a nuclear power plant (NPP) during an accident.
Silylation with smaller organosilanes (trimethyl chlorosilane) resulted in decrease in surface area as they diffused through the pores; however, bulkier silane reacted with surface hydroxyl groups and maintained the pore structure.
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