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The alkali metals can also react analogously with the heavier chalcogens (sulfur, selenium, tellurium, and polonium), and all the alkali metal chalcogenides are known (with the exception of francium's).
Accordingly, analogously prepared hexaphenylbenzene-based diphosphonate 18 reacted with aldehyde 12 to produce 3 in 32.0% yield. Figure 2 Synthesis of compounds 1, 2, and 3. (a) Phenylacetylene (5), Pd PPh3)2CuI, CuI, (Et 3 N, 50°C, 1 h, 92.5%.
[{Zr L (O iPr 2}2] (7) was synthesized analogously by reacting Zr O iPr 4⋅ iPrOH with L H2 in toluene.
reacted predictably.
Brighton reacted.
O'Neal reacted swiftly.
Judge Hughes reacted incredulously.
Europe reacted swiftly.
Forbes: Reacted?
"He has reacted well.
Formation of the aza-ylide intermediate (7) proceeded analogously to the Staudinger reduction; however, the ester group offered a new path of reactivity in which the nucleophilic nitrogen atom reacted with this electrophilic trap to form intermediate 8, which, upon hydrolysis, yielded a stable amide-linked product (9).
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