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In this paper we show that these can be explained by combining classical reaction diffusion theory involving just two reactants (oxidant and reductant), and a secondary reaction in which a reactant on one side of such a front is (re- formed on the othere- formedthe frontheia diffusiother itsideofucthecross the front.
The results obtained have revealed that the measured conversions are preferentially determined by diffusion of formic acid through the top and intermediate layers to the reaction zone on one hand, and by concentration gradient of gaseous reactant on the other hand.
The effect of the volatility of the liquid reactant on the effectiveness factor was also observed.
Methods for determining the effects of stopped-flow intervals and reversible desorption of reactant on observed rates were also developed.
Complementary experiments with pulses of reactant on a fixed-bed reactor allowed to establish the best temperature to obtain maximum sensitivity to hydrogen transfer.
In the case of PANI NFs, the effects of the reaction time, the size of the interfacial area, scale ratio, and concentration of reactant on the crystalline structure, thermal stability, morphology, electrical conductivity and dielectric permittivity are systematically studied.
Similar(42)
It is based on surface reactions, which calls for the adsorption of at least one of the reactants on the catalyst surface.
A speculative model is introduced, which can explain these overshoots by a slow adsorption of one of the reactants on the active sites of the catalyst.
The influence of adsorption parameters such as adsorption temperature and pressure, presence of the O2 co-reactant on the nature and relative surface abundance of the resultant mono- and dimeric NO species was elucidated.
This result also indicates the kinetically sluggish for the association of OH reactants on electrocatalytic active sites in the presence of O2-Cat-2.
The significance of the compositions of reactants on the yield has been determined.
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