The activity enhancement of PdSnAg/C can be rationalized by the synergistic effect of Pd-SnO2-Ag clusters on the superficial surface of catalyst, such as bi-functional mechanism, superior electronic structure, excellent electric conductivity, etc.
This transition can be rationalized by considering the effect of the optical properties of the turbid medium on the angular distribution of remitted light; this concept has been described in detail previously by Bargo et al. [ 33].
This anomalous decrease in charge-transfer resistance can also be rationalized by the "ion gating" effect when considering a single-stranded DNA as a flexible molecule as opposed to a "rigid rod -like strod -likeor the double-structureDNA.
Decreases in the kH2O2/ ktrxsh ratio resulted in steeper changes in the reduced thioredoxin and oxidized Tpx concentrations showing that the ultrasensitive response can be rationalized by considering the effects of increases in the thioredoxin reductase concentration on the Tpx moiety pool.
This shift in absorbance is well-known and has been rationalized by the so-called polaritonic effect caused by a phase retardation of the electromagnetic waves (also known as extrinsic or electrodynamic effect) [13].
Considering faster reduction of Rh oxide in contrast to slower reoxidation of Rh on ZrP2O7, the perturbation effect could be rationalized by the stabilization of metallic Rh species, which is more active than Rh oxide for the catalytic NOx reduction.
6h On the other hand, the ortho effect has been rationalized by the bulkiest aryl group occupying the equatorial position in the T-shaped intermediate, because this position is less crowded than the apical position.
These different salt effects on the nonspecific and two specific complexes can be rationalized by the crystallographic finding that extensive nonelectrostatic contacts are formed in the specific complexes, which must be broken prior to dissociation.
These dependencies may be rationalized by the different sample morphologies.
This might be rationalized by the availability of nitro group at carbon (4') for inter-molecular interactions.
