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In a "wall-less" reactor when a sufficient rate of chain initiation can be reached at temperatures above 800 K, this equilibrium is shifted to form alkyl radicals.
The results clearly reveal a small but significant effect of tensile loading on the rate of chain scission: G(S) stressed/G(S) unstressed ≈ 1.2.
This decrease is due to either the CTA quenching the mid-chain radicals or a reduction of the rate of chain transfer to polymer relative to (chain-end) propagation.
Therefore, low resistance and high extensibility are observed when the rate of chain slippage is much greater than the rate of elongation of the chain.
However, if the rate of chain slippage is relatively low, meaning chains slippage occur insufficiently rapidly in response to the applied stress, the chains will break resulting very short distance of elongation.
If both alpha and beta thalassaemia are inherited together, there may be an amelioration of symptoms due to a balancing out of the rate of chain synthesis.
Similar(48)
Thus, the strategies used by Mycobacterium fortuitum to regulate ribosomal protein synthesis were investigated, including evaluations of the rates of chain elongations of 16S rRNA, rplL and ribosomal protein S12 (rpsL).
When the draw rate is faster than the retraction rate (1/τb) of chain segments, the drawing-induced extended conformation can be found.
The relative constants ktrAkp (ktrA = rate constant of chain transfer to AIR3, kp = rate constant of propagation) were determined by kinetic study.
For the simple shear flow, shear rate dependencies of chain's size, shape, and rotation were monitored.
Rate constant of chain transfer.
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