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The low reactivity of methylcyclohexane, despite its high initial rate of abstraction, is likely a result of the stability of the tertiary radical.
Rate of abstraction of a benzylic H atom dominates that of a secondary H atom with negligible abstraction of the primary H atom at T ⩾ 600 K.
The rapid decline in groundwater resources shows the limitations of this agricultural development strategy and questions its sustainability unless policies change and the rate of abstraction is changed so as not exceed the recharge rate.
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In the past, when there were lower rates of abstraction, the water tables would have remained high enough during the drought for the springs to persist and the water to keep flowing.
At low and intermediate temperatures, the rate of H abstraction from the methylene site in EA exceeds the corresponding values for propane and ethanol.
Since NPPOC photolysis proceeds via a photoinduced β-elimination pathway that is favored by a small concentration of an amine base,[ 19b, 23] the rate of proton abstraction could be limiting under fast deprotection conditions.
The range of abstraction is growing.
Considering that neither mechanism is limited by substrate diffusion but both substrate capture rates are limited by hydrogen atom abstraction (inverse SIE), it appears that the 23-fold faster rate for hydroperoxidation is due to an increased rate of hydrogen atom abstraction compared to the rate of epoxidation.
Recharge rates estimated from the groundwater ages are close to an estimate of the current rate of deep groundwater abstraction.
A competitive kinetic method was used to determine the relative rate of hydrogen atom abstraction by tert‐butoxyl radical to β‐scission.
The magnitude of urbanisation on catchment fluxes is most strongly influenced by urban density and the rate of local groundwater abstraction, which is used for urban irrigation.
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CEO of Professional Science Editing for Scientists @ prosciediting.com