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The adsorbed intermediate of the chloride electrochemical oxidation process on a RuO2TiO2 mixed oxide electrode was studied by cv technique in a large range of sweep rate.
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A range of sweep rates and limiting positive potentials have been used.
The peak-to-peak potential separation is about 100 mV at scan rates below 50 mV s−1, suggesting facile charge transfer kinetics over this range of sweep rates.
Digital simulation of the catalytic voltammetry was achieved with single set of enzyme-dependent kinetic parameters that reproduced the experimental data across a range of sweep rates, and sulfite and mediator concentrations.
The influence of adsorption time, potential, sweeping range and sweep rate on voltammetric CO charge determination is studied.
Different design considerations such as sweep waveform, frequency range and sweep rate are discussed.
In the simulation result, chorus emissions with rising tones are reproduced, while the frequency range, sweep rate, and the amplitude profiles of the reproduced elements are consistently explained by the nonlinear wave growth theory.
Chorus emissions with rising tones are reproduced in the simulation result, while the frequency range, sweep rate, and the amplitude profiles in the spectra of the reproduced elements are consistently explained by the nonlinear wave growth theory.
Factors affecting this include the number of points per sweep and the rate and initial range of sweeps.
The CV curves were acquired in the voltage range of 0 to −1.15 V vs Hg/HgO at the sweep rate range of 5 to 50 mV s−1, and the galvanostatic measurement of the cell was characterized at the current density from 0.5 to 5 A g−1.
Excessive sweep rates are shown to inflate estimates of system loss factors above the true values in proportion to the square root of the sweep rate.
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