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The existence of such a bulk structural component is postulated by random bonding model (RBM).
We could then establish an empirical relation between the [N]/[Si] ratio and n based on the random bonding model on pure SiN x which manifestly differs from previous relations that concerned SiN x :H because of the H incorporation induced by the chemical deposition techniques.
On the basis of FT-IR analysis, it was determined that the structure of the SiOxNy film was a random bonding model (RBM) structure and an increase in the nitrogen gas flow ratio caused an increase in hydrogen termination in the Si O N network.
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Fig. 9 Effect of random bond addition to chemical similarity method performance.
We observed a monotonic decrease in the accuracy of GRAPE/GARLIC with the addition of random bonds between or within residues to hypothetical modular natural product structures, with each random bond associated with a 5.42% decrease in accuracy.
The performance of GRAPE/GARLIC was equivalent to that of the average circular fingerprint with the addition of 2.99 random bonds, the average topological fingerprint with the addition of 4.91 random bonds, and the average substructure keys-based fingerprint with the addition of 2.80 random bonds.
Trend in percentage of correct matches after substitution of a single monomer in hypothetical libraries of linear hybrid natural products with one to eight random bonds.
Random bond and site bond percolation models were employed to quantify the results of bulk and solution polymerizations, respectively, during the sol-gel phase transition.
In order to quantify the limitations of a retrobiosynthetic approach to similarity search, we added random bonds between any two atoms in natural product structures, simulating the effect of a tailoring reaction which violates the retrobiosynthetic logic built into the GRAPE algorithm (Fig. 9).
For each choice of threshold, the network outperforms the expected value obtained a network with uniformly chosen random bonds (blue, circles).
In pathological networks, such as the random bond network [ 11], there are no redundant constraints until the network all at once transitions from floppy to rigid.
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