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The γ′ rafting process is shown to be highly sensitive to the sign and magnitude of the stress triaxiality.
Our simulations reveal that the rafting process is considerably slower in CMSX4 than in CMSX6.
This indicates that plasticity plays a dominant role in the rafting process as compared to elastic modulus mismatch between γ and γ′ phases, which has been ignored in the present simulations.
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The RAFT process enables access to polymer chains with narrow molar mass distributions and high conversions.
The RAFT process is a versatile method for conferring living characteristics on radical polymerizations providing unprecedented control over molecular weight, molecular weight distribution, composition, and architecture.
Hyperbranched glycopolymers of varying molecular weights and compositions are synthesized via reversible addition fragmentation chain transfer (RAFT) process and are further explored for their gene expression in vitro.
A series of block copolymers of styrene, maleic anhydride and acrylic acid were synthesized by the reverse addition fragmentation chain transfer (RAFT) process.
Not even at very high monomer conversions and for large star molecules, a shielding effect of growing arms hampering the RAFT process could be identified.
Coupled size exclusion chromatography (SEC)–electrospray ionization mass spectrometry (ESI-MS) was applied to carefully map the product spectrum of a series of acrylate free radical polymerizations mediated via the reversible addition fragmentation chain transfer (RAFT) process.
Cationic nanogels of Pegylated poly(N,N′-Dimethylaminoethyl methacrylate) (PEG-PDAEMA) have been synthesized in aqueous solution by a one-step surfactant-free reversible addition-fragmentation transfer (RAFT) process.
Dihydroxy terminated poly(dimethyl siloxane) (PDMS) was modified to form a di trithiocarbonate) functional molecule capable of forming tri-block copolymers via the reversible-addition-fragmentation chain transfer (RAFT) process.
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