Exact(5)
To see directly the relative importance of the thermal decomposition versus the destruction by free radicals (i.e.: H, O, OH) iodine was added to the reactant mixture suppressing the radicals' concentrations towards their equilibrium concentrations.
The results show that adding (1000 ppm) NO enhances both low and intermediate temperature ignition delay times by the rapid OH radical pool formation (one to two orders of magnitude higher OH radicals concentrations are observed).
Free radicals concentrations in the non- and sterilized herb samples were compared.
The similar order of free radicals concentrations characterize the non- and sterilized herb samples (Table 1, Fig. 6).
g-Values, linewidths (ΔBpp), and free radicals concentrations (N) in the tested sterilized drugs are compared in Table 1 and in Figs. 4, 5, and 6.> Amplitude (A) of EPR lines of caraway decreases after sterilization, and its values increase after sterilization for curry, curcuma, and cardamom (Fig. 4).
Similar(55)
Grafting reaction is initiated by free radicals and its reaction rate is depended mainly on the free radicals concentration of thermal decomposition of HPP.
A theoretical kinetics model was developed to determine conditions under which the spin-adduct DMPO-OH is not further oxidized by Fe3+ and excessive radicals, so that hydroxyl radicals concentration could be accurately inferred.
Influence of physico-chemical properties of gas and liquid as well as experimental conditions on maximum temperature and free radicals concentration have been then derived.
The ESR measurements gave the free radicals concentration.
Free radicals concentration (N) in all the tested herbs increase after sterilization (Fig. 6, Table 1).
A spectrofluorimeter (Carry Eclipsce, Varian) was used to measure free radicals concentration in the samples.
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