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It was found that quantitative conversions were possible in despite of a carboxylic acid absence.
The polymerization rates at 30 °C were very fast and typically gave quantitative conversions.
Isolated yields confirm high selectivities of more than 90% with quantitative conversions.
Among the various sorbents studied, MCM-41 proves to be the potential candidate and offered quantitative conversions.
The strong catalysis by the high concentration of tertiary amine groups facilitates quantitative conversions at the end of the first stage.
Polymerization of the ε-caprolactone (CL) and δ-valerolactone (VL) proceeds with quantitative conversions, and high molecular weight polyesters (Mn in the order of 104) with moderate polydispersity (Mw/Mn≤1.81) can be obtained at 150 °C in two hours using a CL/Hep molar ratio of 20,000.
Similar(51)
Yield: quantitative conversion.
Products were obtained in high to quantitative conversion yields.
The Ru phosphine-diamine system allowed quantitative conversion and around 50% e.e.e
Both quantitative conversion (>99%) of benzyl alcohol and selectivity (>98%) with respect to benzaldehyde were achieved.
Aryl-TBDMS terminated polymers were reacted with aryl sulfurofluoridate compounds with a near quantitative conversion.
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Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com