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After Pt deposition and lift-off, the Pt samples were selenized via a TAC method.
Matrix spiked analyses of PT samples demonstrated that 99% recovery of target analytes was achieved.
The sputtered Pt samples may obtain a preferential orientation after extended potential cycling in electrolyte solutions due to electrochemical faceting.
A TAC process was used to synthesize layered PtSe2 thin films, as described in our previous work.32,33 The sputtered Pt samples and the Se source (Sigma-Aldrich) were placed in two separate, independently controlled heating zones of a quartz tube furnace.
The primary heating zone where the Pt samples were located was heated to 400 °C and the second heating zone for the Se source was heated to the melting point of Se (~220 °C) under Ar/H2 (9:1) gas flow, leading to the formation of layered PtSe2 thin films.
The treated and untreated Pt samples were analyzed with X-ray diffrAugern, Augelectronron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM).
Similar(26)
% Pt sample showing the highest activity and stability.
We describe a novel HLA-DPB1 allele identified in an ASHI proficiency testing (PT) sample.
Stability tests at 800°C showed that the Pt sample was the only stable catalyst, significant carbon deposition occurring on the other samples.
Modification of the mono-metallic Pt sample by the impregnation of aqueous metal salts and various pre-treatments, resulted in 140 bimetallic catalysts that were used in the hydrogenation study.
Pt Fe alloy as a cathode catalyst suggest that it contains a higher proportion of platinum active sites with a distinctly different nearest neighbor environment in relation to non-alloyed Pt sample [26, 27].
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