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It is proposed that the proton diffusion, dissolvation and protonation of the film may be essential to the electrochemical reduction reaction of the film.
Merinov, B. & Goddard, W. III Proton diffusion pathways and rates in Y-doped BaZrO3 solid oxide electrolyte from quantum mechanics.
As mobility of these buffers is lower than for the H+ ion, they restrict proton diffusion.
F1F0ATPase is therefore reversible, either using the energy of proton diffusion to combine ADP and Pi or using the energy of ATP hydrolysis to pump protons out of the matrix.
In the oxidized state, the proton diffusion may be rate determining, imparting dependence on pH.
A larger structure distortion was found in Nano-E, offering more vacancies for proton diffusion.
The crystallite size of ramsdellite was assumed to be the proton diffusion length.
This phenomenon probably supports proton diffusion, especially in low temperature regions.
The first, thermally activated with an energy around 0.5 eV, emerges at low temperature due to the proton diffusion within the oxide material.
A consistent picture evolves that might guide pore network design strategies for obtaining low percolation thresholds for solvent and proton diffusion.
The thickness of the diffusion layer, the diffusion coefficient and the temperature dependence of proton diffusion were measured.
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