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Equilibrium constant in the chain propagation reaction.
Rate constant of attachment in the chain propagation reaction.
Rate constant of detachment in the chain propagation reaction.
Open image in new window Figure 13 Propagation reaction of peroxy diradical with styrene monomer.
Open image in new window Figure 15 Propagation reaction of polystyryl anionic radical.
Open image in new window Figure 14 Propagation reaction of polystyryl cationic radical.
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Some procedures for simultaneously considering both initiation and autocatalytic propagation reactions were proposed.
It was observed that above this ceiling temperature homopolymer propagation reactions are no longer occurring.
The overall objective of the work was to determine the extent to which the ester side chains of the methacrylate monomers hinder chain-end radical propagation reactions through the pendent vinyl groups of the crosslinking monomer.
Activation energies Ep were in the range of 35.7 to 39.6 kJ mol−1 for DMMn propagation reactions and 50.8 to 54.7 kJ mol−1 for DMMn decomposition, with the difference of −15.1 kJ mol−1 determined by Arrhenius equation.
Modeling results indicate that this behavior is caused by the β-scission of the neopentyl radical and the chain propagation reactions of the hydroperoxyl-neopentyl radical.
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