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Palladium-catalyzed aryl Suzuki and Stille cross-coupling reactions have been surveyed to proceed with complete retention of fluoroalkene geometry, and permit the direct incorporation of a variety of aryl and heteroaromatic substituents.
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When applied to chiral allylic sulfides, the reactions proceed with complete transfer of chirality.
If the data are MCAR, then we will proceed with complete case analysis.
In a rare example of a cross-coupling to give products with vicinal tertiary centers, Liu and co-workers reported the stereospecific Cu-catalyzed reaction of secondary tosylates with primary or secondary alkylmagnesium halides; the reactions proceed with complete inversion of configuration.
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All polymerizations proceeded with complete ring-opening up to approximately 25% conversion, where insoluble polymer was formed.
With the potassium salt the reaction proceeds with complete regio- and diastereoselectivity for the desired product.
This reaction proceeds with complete regioselectivity in the case of terminal alkynes and with moderate selectivity for internal alkynes, yielding a mixture of cyclic acetals 13/ 13/.
After vessel and duct resection, the decision was made to proceed with the complete removal of the infected gland.
MacBride told me that he expected Mueller to proceed with "dispatch and complete thoroughness".
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