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Mo(CHCMe2Ph)(N-2,6-iPr2C6H3)(OCMe(CF3 2) was found to be an effective initiator in order for this polymerization to proceed to the complete conversion.

The reaction was first allowed to proceed to ≈25 % conversion to allow the determination of an initial rate from the linear reaction phase.

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In the presence of sufficient amounts of the inistab, the polymerizations proceeded to high conversion to yield the polymeric product as a powder.

However, ozonolysis of an aqueous sulphonate surfactant solution does produce a species that forms radicals on thermolysis and these radicals initiate radical polymerization of MMA, which proceeds to high conversion in emulsion.

Since the hydrosilylation proceeded to high conversion without the formation of by-product, desired epoxy functionality could be obtained from the starting PMHS with the same Si-H functionality.

Based on integration of the major peaks, the NCL reaction proceeded to 46% conversion of the CysPA.

Thus, CL ROP using 1 with 10 % added epoxide (CHO) at 80 °C proceeded to complete conversion (>99 %) within 2 h, yielding only PCL.

The block copolymerization proceeded to intermediate conversions with narrow polydispersities, however at higher conversions some molecular weight broadening was observed and this was attributed to radical-radical termination reactions.

Monobrominated polystyrene (PStBr) chains were prepared using standard atom transfer radical polymerization (ATRP) procedures at 80 °C in THF, with monomer conversions allowed to proceed to approximately 40%.