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For conservative growth [8, 20 23] the primary relaxation mechanism is the surface diffusion.
The primary relaxation process ascribed to glass transition shifts to higher temperatures and broadens with increasing degree of hydrogenation.
A significant influence of hyperbranched polyurethane in the blends is observed only in the case of the primary relaxation connected with the high-temperature glass transition.
Contrary to the above mentioned expectation the temperature dependence of ε″ exhibits only the primary relaxation and weak secondary relaxation in the glassy state.
Upon the incorporation of nanocellulose (0.5 wt.%), as observed from infrared spectroscopic and thermal analysis, the phase mixing of hard and soft-segments in the TPU matrix and the primary relaxation temperature have slightly increased due to the hydrogen bonding, interfacial area and nucleation-enhanced by long polar nanocrystals.
To obtain the real slope of the primary relaxation at the high-frequency side of the peak, we subtract the influence of the secondary relaxation.
Similar(51)
During TMF cycling, three stages of stress relaxations were identified: (1) primary stress relaxation; (2) steady stress relaxation; and (3) tertiary stress relaxation; each stage exhibits a distinct microstructural evolution.
Secondary relaxations, the primary α relaxation of the PEA component, interfacial polarization and dc conductivity were studied.
Indeed, recent results have shown that a central inhibition of the sympathetic ANS rapidly reverses cardiac hypertrophy and problems associated with primary LV relaxation [ 43, 44].
The performed investigations have shown that the determination by DSC glass transition temperature as well as the related primary α relaxation process are very similar in all materials and practically not affected by the network formation.
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