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Therefore, the dcIII spectrum also shows signals that are not registered in the carminic acid spectrum: ions at m/ z 400 and 370, attributed to the primary fragmentation of the sugar ring [X − H]− and [X − H]−, as well as another two at m/ z 382 and 352, corresponding to the additional loss of water [X − H − H2O]− and [X − H − H2O]−, respectively.
Primary fragmentation of a peptide bond is either a charge-directed process, which involves a mobile proton migrating to the bond, or a charge-remote process, which is determined by the delicate balance between the total number of available protons and the number of proton sequestration sites (basic amino acids) [14 16].
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This procedure is based on the experimental results of primary fragmentation, burnout and ash formation of coal, using wen-chen hydrodynamic model.
Derived fragmentation: A given horizontal fragmentation on a primary table (the primary fragmentation) induces a horizontal fragmentation of another table based on the semijoin with the primary table.
Primary fragmentation and conversion patterns of the residual char were characterized by periodic retrieval of fuel particles from the bed using a basket.
The main fragmentation effect of the explosion, primary fragmentation, comes from the shrapnels.
Cleavage of β-lactam ring was the main, common, and primary fragmentation observed in the low energy activated CID spectrum of most β-lactams [ 20, 21].
One of syn-sedimentary origin (Hjörleifshöfði) and one derived from primary fragmentation processes (Stóri-Nupur).
The formation of polar phase II conjugates strongly affects the polarity, chromatographic retention, ionization and fragmentation behavior [ 117], because the most polar functional group in the molecule usually induces the primary fragmentation path.
In addition, the primary fragmentation event into b- and y-ions (corresponding to sequences N-term and C-term to the fragmentation position) is often accompanied by a number of additional fragmentation events: the formation of an a-ion by a loss of carbon monoxide from the b-ion; the loss of NH3 or H2O (Kinter and Sherman, 2000).
We maintain separate lookup tables for each (primary and derived) fragmentation of each table.
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