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A series of palladium catalysts supported on ordered mesoporous carbon (Pd/OMC-T) were prepared with a variation of preparation temperature (T = 8, 15, 25, 35, and 45 °C) of ordered mesoporous carbon (OMC).
Higher preparation temperature increased HYD selectivity but decreased DDS selectivity.
The samples with x ≤ 0.2 show a linear relationship between MS and preparation temperature.
Cyclic voltammograms in acid medium show no changes in the profile for different preparation temperature.
It was found that the particle size and shape of the Co@C nanoparticles vary with the preparation temperature.
The selection of surfactant and the preparation temperature were the key factors and were difficult to control.
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Results are presented for a range of acetone vapour activities and sample preparation temperatures, and also for a sample prepared with deuterated acetone.
They showed different structures according to catalyst and preparation temperatures.
Nucleation growth and spinodal decomposition dominate the skin formation at low preparation temperatures, while evaporation-driven skin formation takes place at high preparation temperatures.
The eletrochemical active surface area, as measured by cyclic voltammetry, is found to decrease with increasing preparation temperatures.
Additionally 1T phase of MoS2 is known to show limited stability in ambient environment [39, 41, 43], so its fraction in the hybrids are lower than the 2H phase for different preparation temperatures through XPS calculations.
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