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While parameters close to the final fits were chosen for precision, variation in the results can be introduced by choosing different initial conditions.
Analysis of precision (variation of day, day time, instrument, operator, reagent lots) resulted in a total noise (standard deviation) of 0.16 EP score units on a scale from 0 to 15.
The standards were used to characterize the technical variation associated with each platform, both in terms of technical reproducibility (variation between experimental runs performed on different days) and precision (variation between replicate measurements performed within the same run).
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The precision was estimated by analyzing the intra-day (repeatability) and inter-day (intermediate) precision variations.
It was indicated that the RSD of the precision variations were less than 1.47% for all 18 analytes.
The intraday (repeatability) and interday (intermediate precision) variations for the determination of eugenol was carried out at three concentration levels of 20, 100, and 600??g?mL?1.
The F-measure variations observed for these nine mappers are mainly the result of precision variations, except for Novoalign for which the recall values decreased at high error rates.
The DSS concentration is essentially constant for each sample, and the presence of the DSS methyl group resonance allows for both chemical shift referencing and normalization for any measurement variance arising from, for example, pipetting precision or variation in NMR probe sensitivity due to salt effects.
In VDTS, one standard is used to normalize the spectra for any variance arising from measurement factors such as pipetting precision or variation in intrinsic spectrometer sensitivity from sample-to-sample.
The properties of these results were analyzed in terms of the stability, precision and variation characteristics.
The precision of variation method is further improved by modifying the error.
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