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The sensor elements are fabricated as meso-PSi (pore sizes <50 nm, pore thickness ∼7 μm), with Ag metallic contacts made exclusively at the backside of bulk silicon, and ethanol sensing is achieved by measurement of the real-time capacitance and conductance.
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Table 1 therefore also shows the pore wall thickness d wall, as measured by SEM.
From the TEM image, the average pore wall thickness was calculated to be ~6 nm.
Membrane properties, i.e. pore size, thickness, support layer, and salt rejection were also studied.
Among the structural features that spacer size altered, pore wall thickness and pore face roughness were found to be the most dominant effects on strength and stiffness.
These results suggest that the degradation rate of porous foams can be engineered by varying the pore wall thickness and pore surface/volume ratio.
Further, the results of pore wall thickness distribution are well corroborated by X-ray diffraction.
Using data from XRD and gas sorption analysis, we predict pore wall thickness of catalysts according to formula T w = a 0 − Dv(d).
The NFs have the largest pore wall thickness of the three nanostructures, but this alone may not be the only contributor to the strong decrease of surface area.
The optimization of the reactor design is achieved by determining membrane pore size, thickness and gas pressures which provide conversion and selectivity performance comparable to the industrial requirements.
Although, these composites exhibited similar geometrical properties (porosity, pore size, thickness), large differences in permeation performance were obtained between the membranes.
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