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The population of defect groups on the Silicalite-1 surface was modified by aging of the gel, thermal treatment, ionic exchange and silylation procedure.
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This effect may be due to preferential population of defect-like edge and corner Ru sites by Cu, subsequently limiting the amount of the weakly bound hydrogen on the metal surfaces necessary for ethene hydrogenation.
Repeated impregnation cycles to add more carbon layers, using a slow cooling rate during carbonization, performing carbonization at a low temperature and short time (500 °C and 10 min), and coating the supported membranes with permeable polymers were used simultaneously to reduce the population of defects to a certain extent.
To model heterogeneity in the populations of defects we assumed a log- normal distribution probability function.
In parallel, a rate theory model calibrated on the population of point defect (PD) clusters measured by transmission electron microscopy has shown that the dominant sinks for mobile PDs are PD clusters.
On the other hand, as local curvature is sensitive to the ring defects, 3D tomography is likely to be capable of directly characterizing the population of topological defects.
In particular, the fatigue limit is related to the population of extreme defects and to the material properties expressed by cyclic yield strength and by crack propagation thresholds.
The resulting population of topological defects is estimated based on an ensemble of NPC models, partially addressing the common non-uniqueness problem.
The essence of this method is to generate a large dataset of realistic NPC models by virtual synthesis procedures, from which both the population of topological defects and the S q) can be calculated, and subsequently correlated.
Our results reveal that PL spectrum has multifractal nature and different various population of point defects (sulfur vacancy) on single layer MoS2 change dramatically multifractality characteristics (Hurst, Hölder exponents) of photoluminescence spectrum.
As a result, a GB is likely to contain a nonequilibrium population of point defects.
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