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However, a significantly lower crystal quality leads to poorer charge transfer and lower catalytic performance [17, 42].
This was attributed to poorer charge transport and the lipophilicity of the film limiting the rate of interaction with the co-reactant required for formation of the excited state.
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Furthermore, the WO3 films show relatively poor charge separation properties and weak visible-light absorbance.
Most semiconductor-based photocatalysts show low oxidation activity, mainly because of poor charge separation and transfer.
However, the limited dissociation of photoexcitation at weak electric field and poor charge transport in the polymer affects their applications.
Performance is limited by the low red absorption of organic materials, poor charge transport, and low stability.
However, poor charge separation and low charge carrier mobility hinder the improvement of PEC performance of BiVO4.
However, the photocatalytic activity of bare BiVO4 is still not ideal for practical applications because of its excessive charge recombination, poor charge transport, and slow oxidation kinetics.
Thicker films lead to poor charge separation efficiency due to bulk recombination, while thinner films suffered from poor light absorption and increased interfacial recombination.
These two obtained values are larger than 0.5 m 0 (threshold value), and hence, relatively poor charge carrier transport properties are expected along this specific direction.
Challenges for Fe2O3, as for many larger band gap oxides, include poor charge transfer (extremely short minority carrier diffusion lengths) and large electrochemical over-potentials.
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