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This phenomenon can be attributed to the systematic difference of hydrodynamic radius between the polymer and the polystyrene standard, which is likely smaller in structurally similar polymers.
The number-average and weight-average molecular weight (M n and M w, respectively) were determined with a polystyrene standard calibration.
With the exception of P7 and P14, SEC in CHCl3 versus polystyrene standard showed slight increase of molar mass and comparable dispersity for all hydrogenated polymers.
The resulted triblock copolymer was characterized by size exclusion chromatography (SEC) using polystyrene standard and had anMnof 11 K and a polydispersity of 1.3.
The calibration curve was established by using polystyrene standard sample (molecular weights: 5.51 × 104, 1.39 × 104, 2.97 × 103 and 162, respectively).
A mixture of 10 polystyrene standard samples (molecular weight range: 1700-2 890 000) of narrow molecular weight distribution are analysed by this method.
Similar(46)
bEstimated by GPC THFF, polystyrene standards).
Linear polystyrene standards were used for calibration.
Polystyrene standards were employed for calibration.
The polymers were referenced to polystyrene standards.
A set of monodisperse polystyrene standards were utilized for calibration.
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