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The polymerization index N reaches values above 105.
We discuss the dynamics at the base-pair scale and its pivotal coupling with the polymer one, with a polymerization index running from a few nucleotides to tens of kilo-bases.
The relevance of this ensemble of clusters as a model to study the effect of polymerization on Raman intensities is established in several steps, the most important one being the qualitative reproduction of evolution of the Ip polymerization index with the number of bridging oxygen per silicon.
A further limitation is that polymers having a repeating unit with an undefined polymerization index cannot be represented (or reconciled) using SMILES.
Reconciliation of polymers (which are assigned an arbitrary polymerization index of one in InChI, as mentioned above) requires that the corresponding formulae also match.
One major drawback of the InChI representation is that it is not possible to compute InChI strings for generic chemical structures including R-groups (which SMILES can represent), while polymers are represented in an arbitrary state (with a polymerization index of 1).
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It is also demonstrated that immiscibility-loop phase behaviour can only be observed in blends of constituents having sufficient asymmetry in the polymerization indices.
The degrees of polymerization, polydispersity index, and functionality of PVAc macromonomers were evaluated by gel permeation chromatography (g.p.c).
TBAm and ODAm monomers exhibited a well controlled polymerization (polydispersity index (PDI) below 1.3 for number average molecular weight (Mn) until 30,000 g mol−1) over a wide range of conversion (until 70%), whereas DPMAm conversion remained below 20% partly due to steric hindrance.
To investigate the average properties of the system, the number-, weight-average degree of polymerization and polydispersity index are derived.
The pore distribution of the activated carbons played an important role in the control of the polymerization reaction: polydispersity index always failed in the range 1.1 1.3.
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