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Polymer rigidity, glass rubber transition and asymmetric morphology were correlated.
FTIR has been utilized to examine the effect of polymer rigidity and copolymer composition on the accessibility of functional groups to form intermolecular hydrogen bonds in polymer blends.
Among these are the ion content, size of the polyion and counterion, dielectric constant of the host, Tg of the polymer, rigidity or persistence length of the backbone, position of the ion pair relative to the backbone, steric constraints, amount and nature of added additive (plasticizer), thermal history, etc.
Further physical aqueous solution properties evaluated using steady-state solution shear rheology, dynamic light scattering (DLS), and titration studies proved critical to understanding effects of polymer rigidity and conformation in aqueous solutions [23].
As mentioned above, carboxylated polyanions [22, 25] were synthesized from the deprotection of the precursor copolymers, and fully characterized with respect to molar mass, composition, and intrinsic polymer rigidity.
In addition, other factors such as steric hindrance to adsorption, polymer rigidity and distribution of functional groups in the polymer may play a significant role in the polymer drug interaction.
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Cross-linking of the monomers increases a polymer's rigidity and thermal stability.
Meanwhile it was found that the degree of the probe molecule rotation detectable in the ESR spectrum was dependent on the polymer matrix rigidity and the strength of the hydrogen bonding between the probe molecule and the polymer matrix.
Thermal diffusion coefficient derived in the model can qualitatively explain the experimental observations in the literature regarding the dependence of thermal diffusion of polymers to molecular weight, polymer chain rigidity and viscosity of the solvent.
The semi-rigid stilbene-containing copolymers are a new class of copolymers where the increased polymer backbone rigidity leads to a wide range of polymer properties not attained with flexible polymers.
Hemicellulose provides the connection between lignin and the cellulose fibres, and gives the polymer network rigidity [ 4].
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