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Polymer collapse is studied in the regime far from equilibrium.
We describe the implementation of this algorithm and two applications: two dimensions (2-D) melts and polymer collapse.
Analysis within both the micro-canonical and canonical ensembles shows that, for a chain with sufficiently short-range interactions, the usual polymer collapse transition is preempted by a direct freezing or "folding" transition.
The rate of the rotational diffusion of the radical increased discontinuously during the polymer collapse in the former case but in the latter, a typical linear activation of the thermal motion was observed.
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Thus, below a critical pH the polymer collapsed into a compact globular structure (hypercoil) bringing the fluorophore molecules into close proximity with one another.
Above LCST, the polymers collapsed and nanostructured precipitates were observed on the surface's morphology, increasing the water contact angle.
Water contact angles for these brushes measured at different temperatures reveal that the polymer brushes collapse and dehydrate around 13 °C and 25 °C (TTs), respectively, upon elevating the temperature.
The single-chain polymeric nanoparticles were then facilely prepared via single polymer chain collapse and intramolecular crosslinking reaction of the azide polymer in a dilute solution at room temperature under UV irradiation within several minutes.
These findings clearly show that no long-range interactions are necessary for forcing the polymer to collapse but a purely diffusional motion together with chromatin-chromatin binding affinity suffices to achieve this.
With the new inflatable kind the sheets, made from a stronger polymer, are collapsed to form rows of seven uninflated bubbles connected laterally.
Normalizing temperature with the central block Tg caused the ionic conductivity for the IL-incorporated polymers to collapse onto a single curve, which was an order of magnitude higher than the block copolymer in the absence of added IL.
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