Sentence examples for polarizability effect from inspiring English sources

In specific cases, the polarizability effect has a dominant influence on the P properties.

The polarizability effect consists of an electrostatic attraction between the charge arising on the reaction centre owing to the change of electron distribution in the excited state and the dipole moments induced by this charge in the substituents.

It was demonstrated that a solvatochromic equation with three solvatochromic parameters π*, β and α can be used to evaluate the effects of both types of hydrogen bonding and of the solvent dipolarity / polarizability effect.

The role of polarizability effects in the thermodynamics of complex-formation is discussed.

The first model was proposed by Taft and coworkers and subdivides intrinsic substituent effects on proton-transfer equilibria into field effects, polarizability effects and resonance effects.

Polarizability effects stabilize complexes of larger ligands such as dptn relative to those of smaller analogs such as dien in the gas-phase by more effectively dispersing the cationic charge over the complex.

In-depth knowledge on the impact of the docking chemistry, the molecular polarizability,(38) depolarization effects, and (dipolar) donor- and acceptor substituents has been seen to be of uttermost importance for designing molecular structures that lead to SAMs with the desired characteristics.

The DFT calculations show how aqueous solution dampens out chelate effects for small ligands such as en and tn, and also removes the effects of polarizability seen in the gas-phase.

Henceforth, polarizability of the ions has effect on the elastic constants.

In view of equilibrium condition, the third order elastic constants difference also lead to finite value at Cauchy pressure inferring that polarizability of the ions has effect on the elastic constants: C_{112} - C_{166} ne 0 (64) C_{123} - C_{456} ne 0 (65) C_{144} - C_{456} ne 0 (66) C_{123} - C_{144} ne 0. (67).

The bromine accommodated into the micropores induces the dielectric and structural effects, including a polarizability of the interface layer modification [3].