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The coloring mechanism is based on the crystal field splitting of the Cu2+ d-orbitals in a square planar environment.
Several anonymous Dubins-car like mobile robots travel in a planar environment that hosts a scalar field, like the level of radiation or concentration of a contaminant.
For the obtained copper complex, it is tetracoordinated in a distorted square planar environment with two nitrogen and two oxygen atoms as donor sites.
The molecular structures of H2L, nickel and copper complexes were unambiguously determined by single-crystal X-ray diffraction studies reveal that H2L exists in a zwitterionic form while copper complex has copper centre in a distorted square planar environment.
The crystal structure of complex 1 reveals that the NiII center has a NiN4 distorted planar environment and the 1,5-diazacyclooctane ring takes the unusual boat boat configuration.
Single crystal XRD studies of these complexes suggest that Ni II) and Cu II) are in a distorted square planar environment while the spatial arrangement of donor atoms in Zn II) complex is best described as distorted square based pyramid although significant distortion towards trigonal bipyramid is noticed.
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Besides square planar environments, large coverage of tetrahedral, triangular bipyramidal, square pyramidal, octahedral and hexahedral geometries is presented and addressed.
1, 2, 3 and 4 are Cu dtc 2 moieties in which the copper atoms occupy square planar environments which are connected via weak interactions in axial positions to form centrosymmetric dimers.
Locomotion in planar environments has been probably the main topic of research for snake robots [2 4] and has been extended to motion in planar slopes [5, 6], motion in 3D-space [7, 8], and more broad studies on locomotion [9].
Clearly, if this occurs in planar environments, choices for changing trajectory can only amount to movement that is either left or right, and should not be executed too early where there are substantial corner-cutting benefits to be gained by the predator.
This work has primarily focused on spatial navigation in horizontal planar environments: however, recently, interest has been growing in the means by which larger and more dimensionally complex spaces might be represented and used in navigation (see Jeffery et al. [2] for review).
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