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The kinetics of formation of several metal-complexes M-3 of PiCC 3 was analysed qualitatively.
PiCC 3 is an effective tridentate ligand for biologically important transition metal ions.
This formyl-bilinone displayed a chromophore similar to the one of biliviolin, and of PiCC 3, as well.
YCC 2 was converted into the corresponding PiCC 3 via an efficient two-step procedure involving spontaneous air oxidation in the presence of Zn-ions (Fig. 2).
By this approach, e.g. YCC 2 and PiCC 3 were prepared from the NCC 1, which feature two or three conjugated pyrrolic rings.
Among the phyllobilins, only PiCC 3 (a phyllobila- b, c-diene) has been studied extensively, so far, with respect to its capacity to bind transition metal ions.
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Written for Glasgow Improvisers Orchestra (variable instrumentation: nominally picc, 2 fl, ob, a.sax, t.sax, b.sax, horn, tp, 2 tbn, drumset, elec gtr, acoustic gtr, hp, pf, d, perc,, 2 soprano, vc, 3 cb, electronics).
Currency used is Pak rupees and rates are taken from local standard schedule of rates (PICC [31]).
After separation, desalting, isolation and drying Cj-PiCC (3, 5.5 mg, 8.5 μmol, 2.9%%) was obtained as a red powder, which was characterised, as described below.
The significantly less polar pink-red compound Cj-PiCC (3) was indicated to be a further oxidation product of the YCCs (2 a, 2 b).
Analytical HPLC[ 7] revealed three coloured fractions: yellow Cj-YCC-1 (2 b, rt=15 min), yellow Cj-YCC-2 (2 a, rt=22 min) and pink-red Cj-PiCC (3, rt=35 min).
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