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At phase transition pressure it gets softened.
Away from phase transition pressure and at higher pressures i.e., in B1 phase β again becomes stiff.
At lower pressures, SiC is brittle, above 15 GPa and till phase transition pressure, ductile nature of SiC is observed.
However, recent studies have shown that the noncollinear polarization rotation, occurring at phase transition pressure, can result in the giant piezoelectric response [8, 9].
We evaluate the phase transition pressure by computing the Gibbs free energy G = U + PV − TS for the ZB and RS phases.
On the other hand, above the phase transition pressure (P T = 90 GPa), the Gibb's free energy for B1 system becomes more negative than B3 phase, implying B1 phase will be more stable.
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We have successfully obtained the phase transition pressures and volume changes at different temperatures.
At phase transition pressures, SiC has witnessed a discontinuity in aggregate second-order elastic constants C ij, which identifies the first-order phase transition.
Comparison of Figs. 3 and 4 shows that the effect of temperature on phase transition pressures is smooth when compared to the effect of carbon dioxide concentration.
The phase-transition pressure and volume collapse are consistent with earlier observations.
At phase-transition pressure P and at zero temperature: G B1 = G B3 [29].
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