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Sustained Mn release from the solid phase to solution only in the presence of additional Fe(II) indicates further redox reactions between Fe(II) and lepidocrocite coated pyrolusite, resulting in adsorbed or structurally incorporated Mn being released during lepidocrocite transformation to magnetite.
These methods are designed to determining solvation-free energy that is the reversible work necessary to move a molecule from gas phase to solution [28].Thus, in the present study, applying the Gaussian 98 program package, the quantum chemical computations were done on the combination of MTX with the carbon nanotube [29] and Hartree Fock theory in level of 6-31G.
For these purpose, DGT were deployed in ten calcareous soils for different time periods between 4 h and 21 days and the accumulated P were used to calculate the distribution coefficient for labile metal, Kdl, desorption rate constants (k− 1) and the rate at which the soil system can resupply P from solid phase to solution (Tc) using the DIFS model.
Upon the completion of the chain assembly, the product is released from the solid phase to solution, deprotected, and collected.
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Kd values are the solid phase analog to solution phase equilibrium constants and are widely used to quantify a material's performance for trace collection.
These conditions are associated, in a first phase, to the solution of a generalized Sylvester equation and, in a second phase, to the solution of a Sylvester equation under a constraint that describes the faults decoupling of the corresponding estimation error.
Conversely, the lower percentages of encapsulation efficiency and NP yield obtained with PLA-PCL copolymer might be explained with a partial and fast precipitation of polymer that occurs after addition of organic phase to surfactant solution.
The addition of TFA to the mobile phase to assure solution-phase oxidation of neutral analytes with highly conjugated electron systems has been described elsewhere [ 156, 165].
The barred terms indicate location on the resin (solid phase) as opposed to solution phase.
Stock solution (100 µg/mL) of IS was prepared in DMSO then 200 µL of this solution was diluted to 10 mL with the mobile phase to give working solution 3 (WK3, 2 µg/mL).
One mg/mL stock solution of VNT was prepared in DMSO then diluted 10-folds with the mobile phase to give working solution 1 (WK100100 µg/mL).
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