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These results demonstrate that "entanglement phase separation" proceeds during melt-drawing of UHMW-PE.
At low heating rates, the phase separation proceeds significantly before the gelation occurs, creating more coarsened phases.
By regarding the kinetics and the development of a bimodal distribution, we surmise that the phase separation proceeds via a nucleation and growth mechanism.
By using the evaporation process, the phase separation proceeds slowly via solid liquid demixing and thus leads to a particulate morphology in the membrane.
In the second region between ∼15 and ∼1 μm, the SD type phase separation proceeds in the early stage while the characteristic wavelength of the SD decreases with the film thickness.
As temperature falls and amorphous phase separation proceeds, the compositions of the drug-rich and polymer-rich phases follow the phase line (shown as the dashed curve in Fig. 2B).
Similar(54)
Experimental results showed that, for modifier concentrations close to the critical fraction, the system was directly thrown into the unstable region, even at a low polymerization rate, and phase separation proceeded by spinodal demixing.
The time tps of preparation of domains was chosen to be long enough for phase separation to proceed into the late stage.
A model is suggested whereby phase separation in the copolymers proceeds in a manner similar to crystallization of the homopolymer, implying phase-mixed non-crystalline regions with inhomogeneous mobilities.
As the polymerization of MMA proceeded, phase separation took place via spinodal decomposition (SD).
However, for water-soluble polymer solubility of the gel is limited and hence phase separation occurs as the reaction proceeds (Kazuki Nakanishi and Soga, 1992a).
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