The basic 'Configurational' form fits the same structure to each group but allows all model parameters to differ between them.
Apart from the classical governing equations for mass and energy conservations, and for the force equilibrium in the two bulk phases and on their interface, an additional equilibrium equation for a so-called configurational force is imposed in the two bulk phases and on their interface for the effect of the solution-gel phase transition.
Thermodynamic analyses were carried out for each of the constituent binaries in the investigated alloys (Co Cr, Fe Ni, Mo Mn, etc).. Our experimental results combined with the thermodynamic analyses suggest that, in general, enthalpy and non-configurational entropy have greater influences on phase stability in equiatomic, multi-component alloys.
Toremifene diffusivity through the SiO2 phase into H2O is estimated around 10−13 m2/s, suggesting configurational diffusion through mesopores.
The present investigation demonstrates how configurational entropy stabilises rock-salt type single phase multi-component solid solution oxides.
Through successfully alloying Te at Se sites, material's configurational entropy is obviously increased to optimize phase transition characters and reduce lattice thermal conductivity.
Intermolecular pair distribution functions and atomistic configurational snapshots show that the simulated smectic phase consists of bilayer lamellae with a variety of directions, involving tilted and non-interdigitated chains.
Coil-helix-globule transition occurs when the self-attractive interaction increases within semiflexibe ring chains, and the phase transition is attributed to the competition among the configurational entropy, the bending energy, and the self-attractive interaction.
In the next stage, the global detector models the configurational information of the ensemble of fiducial points.
Only when the alloy microstructure is a single-phase, approximately ideal solid solution does the contribution of configurational entropy to the total Gibbs free energy become dominant.
