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All the manupulations were performed under argon environment using Schlenk line system.
Ball milling of the MgH2 powder (Goldschmidt) was performed under argon atmosphere in a Retsch PM400 planetary ball mill using hardened steel balls and vials.
The milling was performed under argon atmosphere for 15 h at 500 rpm, and the final products were dried at 120 °C for 10 h under vacuum and then stored in the Ar-filled glove box.
All polymerizations were performed under argon atmosphere.
All reactions were performed under argon atmosphere unless otherwise specified.
General: All reactions were performed under argon by using modified Schlenk techniques.
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All ligand exchange reactions were performed under an argon atmosphere.
The cell assembly was performed under an argon atmosphere in a glove box (H2O < 10 ppm).
Briefly, the enriched 47TiO2 was combined with 40% surplus of calcium hydride and the reduction process was performed under constant argon flow at 900 °C for 1 h.
Sensitive reactions were performed under an argon atmosphere.
Annealing was performed under H2 and argon (Ar) atmosphere at 950°C for 15 min.
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