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Deprotection of the benzyl pendant groups successfully provided MC with hydroxyl pendant groups (MC-OH).
Two monomers with hydroxyl or butyrate pendant groups were first synthesized.
The syntheses of three C2 symmetric triptycenes containing two pendant groups are described.
The degree of insertion and the length of the pendant groups were determined.
In order to obtain some structural evidences, different molecules have been grafted on the pendant groups.
The mobility of the pendant groups appears to be independent of tacticity.
These motions include the rotation of hydroxyl and hydroxymethyl pendant groups for PVA and PAA, respectively.
spectra of all polymers confirmed polyacetylene type polymer structure with nitrophenoxymethyl pendant groups.
However, the molecular packing was affected by the introduction of different disubstituted pendant groups.
This relaxation changed significantly with the size and the shape of the disubstituted pendant groups.
One method of synthesizing new materials is to react functional pendant groups on an existing polymer.
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