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This latter metal ion shows a peculiar coordination, with a glutamic acid residue replacing one of the four cysteine ligands that are highly conserved throughout the structural zinc-containing dimeric ADHs.
7 As these classically prepared iron-based catalysts do not possess at least not to the same extent the site-isolated iron atoms with the peculiar coordination environment, the new catalyst indeed illustrates the requirement of suppressing the formation of adjacent (multiatom) iron sites, which typically catalyze the unwanted C C coupling that ultimately leads to coke deposit formation.
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There are difficult and peculiar coordinations I pull off because they are spontaneous and free of concern for effect or technique.
In this chapter, the peculiar contribution of coordination and green chemistry in designing new safer reagents and processes for effective and selective metal dissolution and recovery, will be discussed, highlighting the state-of-the-art on promising effective sustainable lixiviants and the future perspectives of these early-stage multidisciplinary studies.
In this review article, we focus on the synthesis of various pentaphenylcyclopentadienyl ligands and on the peculiar reactivity of such hindered ligands in their coordination to a ruthenium II) center.
A larger coordination with water is probably due to a peculiar corrugation of the exposed surface of this species.
The conceptual separation between computation and coordination in distributed computing systems motivates the use of peculiar entities commonly called connectors, whose task is managing the interaction among distributed components.
It bears a very peculiar network of interactions at the binding site, which revolves around the coordination complex formed by a zinc ion, three hystidine residues, and the inhibitor.
Nevertheless, in the case of Anselm, the very peculiar conjunction of faith and reason was accomplished not so much through any clear intellectual coordination as through the religious energy and saintliness of an unusual personality.
Chromium-based catalysts have been widely examined for polymerization, partial oxidation, and aromatization reaction because of the peculiar characteristics of Cr oxide species on the surface of the support, including oxidation state and coordination environment[12].
Why peculiar?
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Justyna Jupowicz-Kozak
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