Sentence examples for pdo 1 from inspiring English sources

DFT calculations confirm the formation of an n-butane σ-complex on PdO(1 0 1).

This work studies the process development for the purification of PDO (1, 3-propanediol) by SMB (simulated moving bed).

At low coverage, n-butane adsorbs on PdO(1 0 1) in a molecular state that is more strongly bound than n-butane physisorbed on Pd(1 1 1).

We investigated the molecular adsorption and dissociation of n-butane on a PdO(1 0 1) thin film using temperature-programmed reaction spectroscopy (TPRS) experiments and density functional theory (DFT) calculations.

For methane, we predict that coordination with a cus-Pd atom lowers the barrier for C H bond cleavage on PdO(1 0 1) by more than 100 kJ/mol.

This molecularly adsorbed state of n-butane on PdO(1 0 1) corresponds to a σ-complex that forms on the rows of coordinatively unsaturated (cus) Pd atoms of the oxide surface.

Carbon recovery was calculated from the ratio of (carbon out)/(carbon in) where the formula C4H7O2N (Zeng et al., [1993]) was used for C. butyricum biomass; Y, Yield; PDO, 1,3-PDO; Buty, butyrate; Acet, acetate.

The data were well reproduced using spectra of metallic Pd (38 at.%) and PdO (62 at.%).

a Fitting results combined b PdO (62 at.%) and c Pd foil (38 at.%).

According to the literature, the Pd+2 (PdO) 3d5/2 and 3d3/2 binding energy values are around ∼337.0 and ~342.0 eV, respectively [28].

XPS measurements also revealed that PdO, Rh2O3 and PtO2 are the main phases in the mono and bimetallic catalysts.