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However, after the application of B⊥, the peak potential, the oscillatory region and the passive potential shift negatively.
Semiconductor behaviour due to the oxygen nonstoichiometry with Nernstian pH dependence is obtained over almost the whole passive potential region.
Mechanical and chemical wear loss has been calculated by modeling and measuring anodic current at open circuit potential and passive potential respectively.
The maps were based on data from a pin-on-plate geometry tested in a 0.5 M solution of H2SO4 at passive potential polarization.
Contrary to published AES studies but consistent with XPS results enrichment of molybdenum in the active and low passive potential region was observed.
It was found that tin dissolves both in the active and partly passive potential region in the form of bivalent tin.
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Results show that cathodic polarization yields larger BSA adsorption than what reported at passive potentials.
The exposed steel then anodically dissolved into the electrolyte to form FeO−2 ions at the passive potentials, and the current potential curve exhibited a humped shape.
The passive oxide layer should then change as a function of its concentration and so the present study is designed to examine its contribution with passive potentials after having observed the effects of dissolved oxygen and pH.
Nanoporous films have been formed on 316L stainless steel in 5 mol dm−3 sulphuric acid at 60 °C by square wave pulse polarization between active or transpassive and passive potentials, and characterized using glow discharge optical emission spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, Rutherford backscattering spectroscopy and nuclear reaction analysis.
Cyclic polarization test results showed a wide trans-passive potential region (> 2 V) for PMMO.
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