Exact(18)
These component meta-entities may also contain other subcomponent meta-entities and complexes, adding depth and complexity to the parent complex.
The parent complex 1 with non-substituent on PBI ligand has also been presented for a better comparison.
The anodic transfer coefficients were also extracted from this analysis, revealing ideal α = 0.50 for the parent complex, to 0.70 ≤ α ≤ 0.88 for complexes with substituted ligands.
Molecular dynamics simulations are performed for the barnase barstar parent complex and seven experimental alanine mutations from the literature, in order to introduce relaxation before and after mutation.
The solution chemistry was characterized and the complex was found to be more stable at neutral pH and to have a different lability pattern than the parent complex.
The peptide binds zinc II) via two deprotonated Cys-thiol groups and one of the Asp-carboxylates in the ZnL parent complex, possessing a remarkably high stability (logK = 9.93).
Similar(42)
The structural consequences drawn from the CD spectra for the mono and bis parent complexes were supported by theoretical calculations.
This because the reduction potentials of the former species occur at potentials similar to or less negative than the latter parent complexes.
Volatility and thermal stability have been studied for some representative members of the series, in correlation with their crystal structures and thermal behaviours of the parent complexes.
The flexibility explains previous experimental findings on the lack of inter-residual strain and the abundance of the ternary over the parent complexes determined in aqueous solutions at physiological pH values.
The chemical transformations in MeCN of the two neutral species Cr CN)(CO 5 (Ib) and Cr(I)(CO 5 (IIb) were studied by cyclic voltammetry immediately after their generation by one-electron oxidation in a flow cell of the parent complexes Ia and IIa.
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